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Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer PdII and PtII Hydrides

  • Wilson Bailey
    ,
  • Werner Kaminsky
    ,
  • Richard A. Kemp
    ,
  • Karen I. Goldberg
  • University of Washington
    ,
  • University of New Mexico
    ,
  • Sandia National Laboratories
Research Output: Contribution to journal Article Peer-review

Abstract

The synthesis and characterization of anionic, neutral, and cationic hydride complexes of platinum and palladium are reported utilizing the PNP (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine) ligand. Comparisons by IR spectroscopy and X-ray crystallography are made across the series. Evaluation of the metal hydride stretching frequencies of the cationic through anionic complexes shows a trend of increasing M–H bond activation. The reactivity of these metal hydrides with oxygen is evaluated and compared to previously reported oxygen insertion reactions.

Bibliographic Information

Output type

Research Output: Contribution to journal Article Peer-review

Original language

American English

Pages from-to (Number of pages)

Pages 2503 (2509 pages)

Journal (Volume, Issue Number)

Organometallics (Volume 33, Issue 10)

Publication milestones

  • Published - 05/05/2014

Publication status

Published - 05/05/2014

ISSN

0276-7333

Publication IDs

  • Scopus: 84901455891